Rotores Moleculares Basados en Hemitioindigo Impulsados por Luz: Aspectos Destacados Aspectos Destacados
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abr 23, 2024
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https://doi.org/10.30878/ces.v31n0a18
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José Juan García Sánchez
http://orcid.org/0000-0002-6415-7854
Samanta Estefania Cruz Ángeles
http://orcid.org/0000-0001-6352-4483
http://orcid.org/0000-0002-6415-7854
Samanta Estefania Cruz Ángeles
http://orcid.org/0000-0001-6352-4483
Resumen
Los rotores moleculares son una subclasificación de las máquinas moleculares y son fundamentales para el desarrollo de tecnologías innovadoras en diversos campos. Este artículo explora exclusivamente los rotores moleculares basados en hemitioindigo (HTI) impulsados por luz, sus variedades, rutas sintéticas, mecanismo de fotoisomerización, y sus propiedades físicas, químicas y fotocrómicas. Para ello, se realizo un análisis de carácter exploratorio, del cual se concluyo que, una de las propiedades que les otorga a estos rotores ventaja sobre otras estructuras es su rotación unidireccional extremadamente rápida al ser irradiados con luz visible, además que sus múltiples perspectivas de aplicación y desarrollo derivadas del aprovechamiento de sus propiedades hacen de estos compuestos una interesante propuesta de innovación en investigación científica.
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GARCÍA SÁNCHEZ, José Juan; CRUZ ÁNGELES, Samanta Estefania.
Rotores Moleculares Basados en Hemitioindigo Impulsados por Luz: Aspectos Destacados.
CIENCIA ergo-sum, [S.l.], v. 31, abr. 2024.
ISSN 2395-8782.
Disponible en: <https://cienciaergosum.uaemex.mx/article/view/16644>. Fecha de acceso: 25 jun. 2025
doi: https://doi.org/10.30878/ces.v31n0a18.
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Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-SinObrasDerivadas 4.0.
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Gerwien, A., Reinhardt, T., Mayer, P., & Dube, H. (2017). Synthesis of double-bond-substituted hemithioindigo photoswitches. Organic Letters, 20(1), 232-235. https://doi.org/10.1021/acs.orglett.7b03574
Gerwien, A., Mayer, P., & Dube, H. (2018a). Photon-only molecular motor with reverse temperature-dependent efficiency. Journal of the American Chemical Society, 140(48), 16442-16445. https://doi.org/10.1021/jacs.8b10660
Gerwien, A., Schildhauer, M., Thumser, S., Mayer, P., & Dube, H. (2018b). Direct evidence for hula twist and single-bond rotation photoproducts. Nature Communications, 9(1), 2510. https://doi.org/10.1038/s41467-018-04928-9
Gerwien, A., Mayer, P., & Dube, H. (2019). Green light powered molecular state motor enabling eight-shaped unidirectional rotation. Nature Communications, 10, 4449. https://doi.org/10.1038/s41467-019-12463-4
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Guentner, M., Schildhauer, M., Thumser, S., Mayer, P., Stephenson, D., Mayer, P. J., & Dube, H. (2015). Sunlight-powered kHz rotation of a hemithioindigo-based molecular motor. Nature Communications, 6(1). https://doi.org/10.1038/ncomms9406
Hashidzume, A., Yamaguchi, H., & Harada, A. (2014). Cyclodextrin-Based Molecular Machines. Molecular Machines and Motors, 71-110. https://doi.org/10.1007/128_2014_547
Heard, A. W., & Goldup, S. M. (2020). Simplicity in the design, operation, and applications of mechanically interlocked molecular machines. ACS Central Science, 6(2), 117-128. https://doi.org/10.1021/acscentsci.9b01185
Hoffmann, K., Guentner, M., Mayer, P., & Dube, H. (2019a). Symmetric and nonsymmetric bis-hemithioindigos – precise visible light controlled shape-shifters. Organic Chemistry Frontiers, 6(8), 1244-1252. https://doi.org/10.1039/c9qo00202b
Hoffmann, K., Mayer, P., & Dube, H. (2019b). A hemithioindigo molecular motor for metal surface attachment. Organic & Biomolecular Chemistry, 17(7), 1979-1983. https://doi.org/10.1039/c8ob02424c
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Jia, S., Fong, W.-K., Graham, B., & Boyd, B. J. (2018). Photoswitchable molecules in long-wavelength light-responsive drug delivery: from molecular design to applications. Chemistry of Materials, 30(9), 2873-2887. https://doi.org/10.1021/acs.chemmater.8b00357
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