Modelo cinético de la hidrólisis de aceite vegetal de Jatropha curcas L para producir ácidos grasos libres Kinetic model of the hydrolysis of vegetable oil from Jatropha curcas L to produce free fatty acids
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jul 9, 2026
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https://doi.org/10.30878/ces.v33n0a71
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Fernanda Velázquez Rodríguez
http://orcid.org/0009-0009-1632-0248
Sara Laurenes García
http://orcid.org/0009-0008-5588-6714
Ignacio Elizalde Martínez
http://orcid.org/0000-0002-8755-5812
http://orcid.org/0009-0009-1632-0248
Sara Laurenes García
http://orcid.org/0009-0008-5588-6714
Ignacio Elizalde Martínez
http://orcid.org/0000-0002-8755-5812
Resumen
Se realiza la estimaci.n de los par.metros cin.ticos de un modelo de ley de potencias de la hidr.lisis
de aceite de Jatropha curcas L para producir .cidos grasos libres considerando dependencia de primer
orden respecto al triglic.rido para lo se utiliz. un reactor discontinuo que oper. entre 30-180 minutos
y 220-260 ÅãC. El an.lisis de los productos de reacci.n se realiz. mediante titulaci.n siguiendo la
norma NMX-F-101-SCFI-2012. Como resultados se obtuvieron la energ.a de activaci.n de 103.846
kJ/mol y el factor de frecuencia de 3.1828x1010 h-1 con un coeficiente de determinaci.n de 0.9981.
Las predicciones del modelo con datos independientes tuvieron un error menor al 5% lo cual valida
el modelo cin.tico desarrollado.
Article Details
Como citar
VELÁZQUEZ RODRÍGUEZ, Fernanda; LAURENES GARCÍA, Sara; ELIZALDE MARTÍNEZ, Ignacio.
Modelo cinético de la hidrólisis de aceite vegetal de Jatropha curcas L para producir ácidos grasos libres.
CIENCIA ergo-sum, [S.l.], v. 33, jul. 2026.
ISSN 2395-8782.
Disponible en: <https://cienciaergosum.uaemex.mx/article/view/26684>. Fecha de acceso: 18 ago. 2026
doi: https://doi.org/10.30878/ces.v33n0a71.
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Ciencias exactas y aplicadas
Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-SinObrasDerivadas 4.0.
Citas
ASTM D1298-12b(2017)e1 Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method. doi: 10.1520/D1298-12BR17E01
ASTM D7042-16e2 Standard Test Method for Dynamic Viscosity and Density of Liquids by Stabinger Viscometer (and the Calculation of Kinematic Viscosity). doi: 10.1520/D7042-16E02
Andari, F., Kittel, J., Fernandes, J., Godin, N., Ter-Ovanessian, B., Ropital, F. (2022). High temperature corrosion in various grades of vegetable and waste oils used for bio-fuel production. Corrosion Science, 206: 110501. doi: 10.1016/j.corsci.2022.110501
Barison, A., Pereira, C., Ramos, F., Simonelli, F., Lenz, C., Ferreira, A. (2010). A simple methodology for the determination of fatty acid composition in edible oils trhought 1H NMR spectroscopy. Magnetic Resonance in Chemistry, 48: 642-650. doi: 10.1002/mrc.2629
Basu, P. (2010) Chapter 7 Hydrothermal gasification of Biomass, In Biomass Gasification and Pyrolysis. Prabir Basu Editor, Academic Press. ISBN 9780123749888
Dos Santos, L., Rodrigues, R., de Oliveira, J., Flumigan, D. (2017) Experimenatl factorial design on hydroesterification of waste cooking oil by subcritical conditions for biodiesel production. Renewable Energy, 114: 574-580.
Elizalde, I., Mederos F. (2018). Propuesta de una secuencia para la modelación matemática conaplicaciones en fenómenos con variación continua típicos de ingniería química. Temas de Ciencia y Tecnología, 22(64): 69-74. ISSN: 2007-0977. Disponible en: https://www.utm.mx/edi_anteriores/temas64/T64_N02_Propuesta.pdf
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Hernández, E., Elizalde, I., Sánchez, F., Reza, C., Ramírez, L. (2025). Oxygen removal from poor-quality refined edible oit to produce hydrocarbon-type biofules using the hydrotreating process. Reaction Kinetics, Mechanims and Catalysis, 138: 1469-1477. doi: 10.1007/s11144-025-02820-4
Kamyab, B., Wang, H., Xu, C., Chambers, D., Bassi, A. (2024). Preparing vegetable oil-based metalworking fluids by hydrolysis-esterification two-step process. Biomass and Bioenergy, 183: 107175. doi: 10.1016/j.biombioe.2024.107175
Machado, S., Da-Ros, P., Castro, H., Giordani, D. (2021). Hydrolysis of vegetable oil and microbial oils catalyzed by a solid preparation of castor bean lipase. Biocatalysts and Agricultural Biotechnology, 37: 102188. doi: 10.1016/j.bcab.2021.102188
Menalla, E., Garcia, J., Cantero, D., Cocero J. (2024). Hydrothermal hydrolysis of triglicerides: tunable and intensified production of dyglicerides, monoglycerides, and free fatty acids. Chemical Engineering Journal, 493: 152391. doi: 10.1016/j.cej.2024.152391
Orozco, F. (1989). Análisis Químico Cuantitativo. Editorial Porrua. ISBN: 9789684320048
Peters, M., Tondo, C., Wang, J., Onwudili, A. (2022). Subcritical water hydrolysis of fresh and waste cooking oils to fatty acids followed by esterification to facty acid methy estres: detailed characterization of feedstocks and products. ASC Omega, 7:46870-46883. doi: 10.1021/acsomega.2c05972
Polo, L., Elizalde, I., Mederos, F., Trejo, F., Ramirez, E., Sánchez F. (2020). Assesing different alternatives by simulation to optimize a homegenoeus transesterifiaction process to improve the produced/consumed energy. Reaction Kinetics, Mechanism and Catalysis, 129:41-56. doi: 10.1007/s11144-019-01713-7
Sakaino, M., Sano, T., Kato, S., Shimizu, N., Ito, J., Rahmania, H., Imagi, J., Nakagawa, H. (2022). Carboxylic acids derived from triacylglycerols that contribute in acidic value during the thermal axodation of oils. Scientific Reports, 12:124600. doi: 10.1038/s41598-022-15627-3
Secretaría de Economía (2012). Alimentos-Aceites y grasas vegetales o animales-Determinación de ácidos grasos libres-Método de prueba. NMX-F-101-SCFI-2012 DOF 2012-09-17. Disponible en: https://platiica.economia.gob.mx/normalizacion/nmx-f-101-scfi-2012/
Shakinova, F., Shishov, A., Bulatov, A. (2022). Hydrolysis of triglycerides in milk to provide fatty acids as precursors in the formation of deep eutectic solvent for extraction of polycyclic aromatic hydrocarbons. Talanta, 237: 122968. doi: 10.1016/j.talanta.2021.122968
Spinsolve (s.f.). Characterizing fatty acids with advanced multinuclear NMR methods. Magritek. Disponible en: https://magritek.com/wp-content/uploads/2020/03/Application-Note-Characterizing-Fatty-Acids-with-multinuclear-NMR-Magritek-060418-back.pdf
The MathWorks Inc. (2024). MATLAB versión 24.1.0.2653294 (R2024a), Natick, Massachusetts: The MathWorks Inc. https://www.mathworks.com
The University of Manchester (s.f.) Mass transfer effects on catalytic reactions. Disponible en: https://www.training.itservices.manchester.ac.uk/public/gced/Cat_mass_trans/cat_mass_trans.html
Velázquez, F., Sánchez, F., Romero, I., Elizalde, I. (2025) Hydrodeoxygenation process to obtaing green naphtha, kerosene and diesel fractions from mesocarp and kernel oil from Elaeis guineensis fruit. Chemical Papers, in press. doi: 10.1007/s11696-025-04152-y
ASTM D7042-16e2 Standard Test Method for Dynamic Viscosity and Density of Liquids by Stabinger Viscometer (and the Calculation of Kinematic Viscosity). doi: 10.1520/D7042-16E02
Andari, F., Kittel, J., Fernandes, J., Godin, N., Ter-Ovanessian, B., Ropital, F. (2022). High temperature corrosion in various grades of vegetable and waste oils used for bio-fuel production. Corrosion Science, 206: 110501. doi: 10.1016/j.corsci.2022.110501
Barison, A., Pereira, C., Ramos, F., Simonelli, F., Lenz, C., Ferreira, A. (2010). A simple methodology for the determination of fatty acid composition in edible oils trhought 1H NMR spectroscopy. Magnetic Resonance in Chemistry, 48: 642-650. doi: 10.1002/mrc.2629
Basu, P. (2010) Chapter 7 Hydrothermal gasification of Biomass, In Biomass Gasification and Pyrolysis. Prabir Basu Editor, Academic Press. ISBN 9780123749888
Dos Santos, L., Rodrigues, R., de Oliveira, J., Flumigan, D. (2017) Experimenatl factorial design on hydroesterification of waste cooking oil by subcritical conditions for biodiesel production. Renewable Energy, 114: 574-580.
Elizalde, I., Mederos F. (2018). Propuesta de una secuencia para la modelación matemática conaplicaciones en fenómenos con variación continua típicos de ingniería química. Temas de Ciencia y Tecnología, 22(64): 69-74. ISSN: 2007-0977. Disponible en: https://www.utm.mx/edi_anteriores/temas64/T64_N02_Propuesta.pdf
Fogler, S. (2022). Elements of Chemical Reaction Engineering (6a. Edición). Pearson. ISBN: 978-1292416663
Hernández, E., Elizalde, I., Sánchez, F., Reza, C., Ramírez, L. (2025). Oxygen removal from poor-quality refined edible oit to produce hydrocarbon-type biofules using the hydrotreating process. Reaction Kinetics, Mechanims and Catalysis, 138: 1469-1477. doi: 10.1007/s11144-025-02820-4
Kamyab, B., Wang, H., Xu, C., Chambers, D., Bassi, A. (2024). Preparing vegetable oil-based metalworking fluids by hydrolysis-esterification two-step process. Biomass and Bioenergy, 183: 107175. doi: 10.1016/j.biombioe.2024.107175
Machado, S., Da-Ros, P., Castro, H., Giordani, D. (2021). Hydrolysis of vegetable oil and microbial oils catalyzed by a solid preparation of castor bean lipase. Biocatalysts and Agricultural Biotechnology, 37: 102188. doi: 10.1016/j.bcab.2021.102188
Menalla, E., Garcia, J., Cantero, D., Cocero J. (2024). Hydrothermal hydrolysis of triglicerides: tunable and intensified production of dyglicerides, monoglycerides, and free fatty acids. Chemical Engineering Journal, 493: 152391. doi: 10.1016/j.cej.2024.152391
Orozco, F. (1989). Análisis Químico Cuantitativo. Editorial Porrua. ISBN: 9789684320048
Peters, M., Tondo, C., Wang, J., Onwudili, A. (2022). Subcritical water hydrolysis of fresh and waste cooking oils to fatty acids followed by esterification to facty acid methy estres: detailed characterization of feedstocks and products. ASC Omega, 7:46870-46883. doi: 10.1021/acsomega.2c05972
Polo, L., Elizalde, I., Mederos, F., Trejo, F., Ramirez, E., Sánchez F. (2020). Assesing different alternatives by simulation to optimize a homegenoeus transesterifiaction process to improve the produced/consumed energy. Reaction Kinetics, Mechanism and Catalysis, 129:41-56. doi: 10.1007/s11144-019-01713-7
Sakaino, M., Sano, T., Kato, S., Shimizu, N., Ito, J., Rahmania, H., Imagi, J., Nakagawa, H. (2022). Carboxylic acids derived from triacylglycerols that contribute in acidic value during the thermal axodation of oils. Scientific Reports, 12:124600. doi: 10.1038/s41598-022-15627-3
Secretaría de Economía (2012). Alimentos-Aceites y grasas vegetales o animales-Determinación de ácidos grasos libres-Método de prueba. NMX-F-101-SCFI-2012 DOF 2012-09-17. Disponible en: https://platiica.economia.gob.mx/normalizacion/nmx-f-101-scfi-2012/
Shakinova, F., Shishov, A., Bulatov, A. (2022). Hydrolysis of triglycerides in milk to provide fatty acids as precursors in the formation of deep eutectic solvent for extraction of polycyclic aromatic hydrocarbons. Talanta, 237: 122968. doi: 10.1016/j.talanta.2021.122968
Spinsolve (s.f.). Characterizing fatty acids with advanced multinuclear NMR methods. Magritek. Disponible en: https://magritek.com/wp-content/uploads/2020/03/Application-Note-Characterizing-Fatty-Acids-with-multinuclear-NMR-Magritek-060418-back.pdf
The MathWorks Inc. (2024). MATLAB versión 24.1.0.2653294 (R2024a), Natick, Massachusetts: The MathWorks Inc. https://www.mathworks.com
The University of Manchester (s.f.) Mass transfer effects on catalytic reactions. Disponible en: https://www.training.itservices.manchester.ac.uk/public/gced/Cat_mass_trans/cat_mass_trans.html
Velázquez, F., Sánchez, F., Romero, I., Elizalde, I. (2025) Hydrodeoxygenation process to obtaing green naphtha, kerosene and diesel fractions from mesocarp and kernel oil from Elaeis guineensis fruit. Chemical Papers, in press. doi: 10.1007/s11696-025-04152-y